SCHEDULED MAINTENANCE
A newly developed methodology for the use of organosilanes as radical precursors under metal-free and visible-light conditions is presented. The strong oxidant character of the 9-mesityl-10-methylacridinium salt in its excited state enables the transformation of simple silanes to the corresponding carbon-centered radicals, which were trapped by various acceptor molecules.
M. Uygur, T. Danelzik and O. García Mancheño, Chem. Commun., 2019, 55, 2980 DOI: 10.1039/C8CC10239B
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