Issue 14, 2019
From the journal:

Chemical Communications

Homogeneously-catalysed hydrogen release/storage using the 2-methylindole/2-methylindoline LOHC system in molten salt-organic biphasic reaction systems†

Alexander Søgaard, ORCID logo ab   Marlene Scheuermeyer,a   Andreas Bösmann, ORCID logo a   Peter Wasserscheid ORCID logo *ac  and  Anders Riisager ORCID logo *b  

* Corresponding authors

a Lehrstuhl für Chemische Reaktionstechnik, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 3, D-91058 Erlangen, Germany

b Department of Chemistry, Centre for Catalysis and Sustainable Chemistry, Technical University of Denmark, Kemitorvet, DK-2800 Kgs, Lyngby, Denmark
E-mail: ar@kemi.dtu.dk
Tel: +45 4525 2233

c Forschungszentrum Jülich, Helmholtz-Institut Erlangen-Nürnberg für Erneuerbare Energien (IEK 11), Egerlandstraße 3, D-91058 Erlangen, Germany

Abstract

Ir-Complex catalysed hydrogen release/storage using a 2-methylindole/2-methylindoline Liquid Organic Hydrogen Carrier (LOHC) system is shown to be effective in a temperature range of 120 to 140 °C. In the form of a liquid–liquid biphasic reaction system with molten [PPh4][NTf2] as catalyst immobilisation phase, the applied cationic Ir-complex can be easily separated and recycled enabling a small amount of ionic catalyst solution to store/release a large amount of hydrogen.

Graphical abstract: Homogeneously-catalysed hydrogen release/storage using the 2-methylindole/2-methylindoline LOHC system in molten salt-organic biphasic reaction systems

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Article information

DOI
https://doi.org/10.1039/C8CC09883B
Article type
Communication
Submitted
13 Dec 2018
Accepted
18 Jan 2019
First published
18 Jan 2019

Chem. Commun., 2019,55, 2046-2049

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Homogeneously-catalysed hydrogen release/storage using the 2-methylindole/2-methylindoline LOHC system in molten salt-organic biphasic reaction systems

A. Søgaard, M. Scheuermeyer, A. Bösmann, P. Wasserscheid and A. Riisager, Chem. Commun., 2019, 55, 2046 DOI: 10.1039/C8CC09883B

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