Issue 32, 2017, Issue in Progress
From the journal:

RSC Advances

Retrieving aromaticity of dithiadiazuliporphyrin by oxidation: illustration by experimental and theoretical investigation†

Young Mo Sung,a   Natasza Sprutta,b   Jun Oh Kim,a   Yun Hee Koo,a   Lechosław Latos-Grażyński*b  and  Dongho Kim ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Yonsei University, Seoul 120-749, Korea
E-mail: dongho@yonsei.ac.kr
Fax: +82-2-2123-2434
Tel: +82-2-2123-2652

b Department of Chemistry, University of Wrocław, 14 F. Joliot-Curie Street, Wrocław, Poland
E-mail: lechoslaw.latos-grazynski@chem.uni.wroc.pl
Fax: +48-713-282-348
Tel: +48-71-3757256

Abstract

The photophysical properties of neutral, monocation radical, and dication of dithiadiazuliporphyrin have been examined with a particular focus on their aromaticity. Dithiadiazuliporphyrin exhibits significantly different characteristics depending on its oxidation state. From these features, we could conclude that the aromaticity of dithiadiazuliporphyrin is changed from nonaromatic to aromatic upon oxidation from neutral to monocation radical and dication by Br2.

Graphical abstract: Retrieving aromaticity of dithiadiazuliporphyrin by oxidation: illustration by experimental and theoretical investigation

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C7RA02458D
Article type
Paper
Submitted
28 Feb 2017
Accepted
24 Mar 2017
First published
03 Apr 2017
This article is Open Access
Creative Commons BY license

RSC Adv., 2017,7, 19502-19505

Permissions

Request permissions

Retrieving aromaticity of dithiadiazuliporphyrin by oxidation: illustration by experimental and theoretical investigation

Y. M. Sung, N. Sprutta, J. O. Kim, Y. H. Koo, L. Latos-Grażyński and D. Kim, RSC Adv., 2017, 7, 19502 DOI: 10.1039/C7RA02458D

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements