Rational serendipity: “undirected” synthesis of a large {MnIII10CuII5} complex from pre-formed MnII building blocks

Jamie M. Frost; Fraser J. Kettles; Claire Wilson; Mark Murrie

doi:10.1039/C6DT03914F

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Rational serendipity: “undirected” synthesis of a large {Mn ^III₁₀Cu ^II₅} complex from pre-formed Mn^II building blocks†

Jamie M. Frost,

^a Fraser J. Kettles,^a Claire Wilson

^a and Mark Murrie

*^a

Author affiliations

* Corresponding authors

^a WestCHEM, School of Chemistry, University of Glasgow, University Avenue, Glasgow, UK G12 8QQ
E-mail: Mark.Murrie@glasgow.ac.uk

Abstract

Use of an aminopolyalcohol-based Mn^II complex in solvothermal Cu^II chemistry leads to a rare example of a high nuclearity heterometallic {Mn^III₁₀Cu^II₅} system, in which four Cu^II(H₁Edte) units trap an inner {Mn^III₁₀Cu^II} oxide core.

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Article information

DOI: https://doi.org/10.1039/C6DT03914F
Article type: Communication
Submitted: 10 Oct 2016
Accepted: 28 Oct 2016
First published: 28 Oct 2016
This article is Open Access

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Dalton Trans., 2016,45, 18094-18097

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Rational serendipity: “undirected” synthesis of a large {Mn^III₁₀Cu^II₅} complex from pre-formed Mn^II building blocks

J. M. Frost, F. J. Kettles, C. Wilson and M. Murrie, Dalton Trans., 2016, 45, 18094 DOI: 10.1039/C6DT03914F

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Dalton Transactions