Issue 16, 2016

Nitro-redox reactions at a frustrated borane/phosphane Lewis pair

Abstract

The unsaturated 1,4-P/B-FLPs 6 reduced nitrobenzene to nitrosobenzene which was directly trapped by an allylboration reaction to give the seven-membered B–O–P compounds 9a and 9b. The FLP 6a reacted analogously with trans-β-nitrostyrene. The products were characterized by X-ray diffraction.

Graphical abstract: Nitro-redox reactions at a frustrated borane/phosphane Lewis pair

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Article information

Article type
Communication
Submitted
03 Mar 2016
Accepted
11 Mar 2016
First published
14 Mar 2016
This article is Open Access
Creative Commons BY license

Dalton Trans., 2016,45, 6820-6823

Nitro-redox reactions at a frustrated borane/phosphane Lewis pair

G. Chen, G. Kehr, C. G. Daniliuc and G. Erker, Dalton Trans., 2016, 45, 6820 DOI: 10.1039/C6DT00857G

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