Issue 25, 2016
From the journal:

Dalton Transactions

Synthesis, characterization, and reactivity of a side-on manganese(iii)–peroxo complex bearing a pentadentate aminopyridine ligand†

Junyi Du,ab   Daqian Xu,a   Chunxi Zhang,*c   Chungu Xia,a   Yong Wang*a  and  Wei Sun*a  

* Corresponding authors

a State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
E-mail: wsun@licp.cas.cn, wangyong@licp.cas.cn

b University of Chinese Academy of Sciences, Beijing 100039, China

c Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China
E-mail: chunxizhang@iccas.ac.cn

Abstract

A manganese(II) complex has been prepared with a proline-derived pentadentate ligand (Pro3Py), and it can be converted to a peroxomanganese(III) complex in the presence of H2O2 and triethylamine. The resulting peroxomanganese(III) complex was well characterised by UV-vis, EPR and ESI-MS techniques, and the geometric structure was discussed based on DFT calculations.

Graphical abstract: Synthesis, characterization, and reactivity of a side-on manganese(iii)–peroxo complex bearing a pentadentate aminopyridine ligand

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Article information

DOI
https://doi.org/10.1039/C6DT00508J
Article type
Communication
Submitted
04 Feb 2016
Accepted
18 May 2016
First published
18 May 2016

Dalton Trans., 2016,45, 10131-10135

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Synthesis, characterization, and reactivity of a side-on manganese(III)–peroxo complex bearing a pentadentate aminopyridine ligand

J. Du, D. Xu, C. Zhang, C. Xia, Y. Wang and W. Sun, Dalton Trans., 2016, 45, 10131 DOI: 10.1039/C6DT00508J

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