Issue 87, 2016

A hexameric [Mn III18Na6] wheel based on [Mn III3O]7+ sub-units

Abstract

A novel hexameric [MnIII18Na6] wheel-like aggregate consisting of [MnIII3O] triangles is reported. It is the second highest nuclearity oxime-based Mn cluster, the largest member of the recently-developed family of molecular oligomers based on [MnIII3O] triangles, and the only one with a wheel-like metal topology.

Graphical abstract: A hexameric [MnIII18Na6] wheel based on [MnIII3O]7+ sub-units

Supplementary files

Article information

Article type
Communication
Submitted
12 Aug 2016
Accepted
23 Sep 2016
First published
23 Sep 2016
This article is Open Access
Creative Commons BY license

Chem. Commun., 2016,52, 12829-12832

A hexameric [MnIII18Na6] wheel based on [MnIII3O]7+ sub-units

M. Manoli, R. Inglis, S. Piligkos, L. Yanhua, W. Wernsdorfer, E. K. Brechin and A. J. Tasiopoulos, Chem. Commun., 2016, 52, 12829 DOI: 10.1039/C6CC06644E

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