A novel protocol for the synthesis of polycyclic compounds from linear diynes and diaryliodonium salts has been realized. The reaction proceeded through Cu-catalyzed arylation of alkynes to generate two vinyl carbocation intermediates that subsequently reacted with arene groups to form fused rings containing diene moieties.
G. Wang, C. Chen and J. Peng, Chem. Commun., 2016, 52, 10277 DOI: 10.1039/C6CC05735G
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