Issue 38, 2015

Facile synthesis of reduced graphene oxide wrapped nickel silicate hierarchical hollow spheres for long-life lithium-ion batteries

Abstract

Layered silicate is a new type of electrode material with high reversible capacity. However, its poor electrical conductivity leads to rapid capacity decay. To solve this problem, reduced graphene oxide (RGO) wrapped nickel silicate (NiSiO) hollow spheres are successfully synthesized. The hollow structure provides sufficient free space to accommodate the volume variation during lithiation/de-lithiation and the RGO improves the electrical conductivity. The resulting NiSiO/RGO delivers a capacity of 400 mA h g−1 at 500 mA g−1 after 1000 cycles, making the NiSiO/RGO composite a promising anode material for lithium-ion batteries.

Graphical abstract: Facile synthesis of reduced graphene oxide wrapped nickel silicate hierarchical hollow spheres for long-life lithium-ion batteries

Supplementary files

Article information

Article type
Paper
Submitted
25 Jun 2015
Accepted
10 Aug 2015
First published
10 Aug 2015

J. Mater. Chem. A, 2015,3, 19427-19432

Author version available

Facile synthesis of reduced graphene oxide wrapped nickel silicate hierarchical hollow spheres for long-life lithium-ion batteries

C. Tang, J. Sheng, C. Xu, S. M. B. Khajehbashi, X. Wang, P. Hu, X. Wei, Q. Wei, L. Zhou and L. Mai, J. Mater. Chem. A, 2015, 3, 19427 DOI: 10.1039/C5TA04680G

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