Issue 17, 2016

Two physical strategies to reinforce a nonmetallic photocatalyst, g-C3N4: vacuum heating and electron beam irradiation

Abstract

Herein, we demonstrated two physical strategies, namely, vacuum heating and electron beam irradiation, to reinforce a nonmetallic photocatalyst, g-C3N4. These two post-treatments also improved the visible light absorption properties of g-C3N4; however, electron beam irradiation was more destructive, and it caused a determined change in the chemical bonds and band structure of the compound. According to the post-processing parameters mentioned in this article, vacuum heating (38 ± 2 mTorr for 4 days at 200 °C) enhanced the photocatalytic efficiency of the original g-C3N4 by 2.5 times, whereas electron beam irradiation (760 kGy at 1.8 MeV and 8 mA s−1) improved it by 4.5 times. Finally, the post-treated photocatalysts were stable during photocatalytic oxidation, which is important for practical applications.

Graphical abstract: Two physical strategies to reinforce a nonmetallic photocatalyst, g-C3N4: vacuum heating and electron beam irradiation

Supplementary files

Article information

Article type
Paper
Submitted
04 Nov 2015
Accepted
03 Dec 2015
First published
15 Jan 2016

RSC Adv., 2016,6, 14002-14008

Author version available

Two physical strategies to reinforce a nonmetallic photocatalyst, g-C3N4: vacuum heating and electron beam irradiation

Y. Zhang, H. Zhang, L. Cheng, Y. Wang, Y. Miao, G. Ding and Z. Jiao, RSC Adv., 2016, 6, 14002 DOI: 10.1039/C5RA22732A

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