Two S = 1/2 one-dimensional barium copper phosphates showing antiferromagnetic and ferromagnetic intrachain interactions†
Abstract
Two barium copper phosphates, BaCu2(PO4)2(H2O) (1) and Ba2Cu(HPO4)(PO4)(OH) (2), were synthesized under mild hydrothermal conditions. The Cu cation in 1 adopts a CuO4(H2O) square pyramidal coordination configuration, forming alternating chains along the b axis through alternative corner and edge sharing, while the geometry of the Cu center in 2 is a CuO4(OH)2 octahedron which further connects each other by edge sharing to constitute uniform chains along the b axis. Magnetic behaviors of both compounds were analyzed by susceptibility, magnetization and heat capacity measurements. The dominant intrachain couplings are antiferromagnetic in 1 with a long-range ordering at 14 K and ferromagnetic in 2 without long-range ordering above 2 K. The first principles calculations indicate that the intrachain ferromagnetic couplings in 2 originate from Cu(1)–O(7)H–Cu(1) dpσ correlation superexchanges. The susceptibility data of compounds 1 and 2 are fitted by using suitable antiferromagnetic chain and ferromagnetic chain models, respectively. In addition, we report the results of the infrared and thermal measurements of both the compounds.
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