Crystal engineering provides tools to the rational design of materials with desired structures or properties. We have exploited the analogy between hydrogen bonds and halogen bonds to trap I2 in the channels of crystal structures, thus stabilizing the otherwise unfavourable tetrahalides via charge transfer interactions.
F. Pan, R. Puttreddy, K. Rissanen and U. Englert, CrystEngComm, 2015, 17, 6641 DOI: 10.1039/C5CE01288K
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