Issue 26, 2016
From the journal:

Chemical Communications

Ca(BH4)2–Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle

N. Bergemann,*a   C. Pistidda,a   C. Milanese,b   T. Emmler,a   F. Karimi,a   A.-L. Chaudhary,a   M. R. Chierotti, ORCID logo c   T. Klassenad  and  M. Dornheima  

* Corresponding authors

a Helmholtz-Zentrum Geesthacht, Institute of Materials Research, Max-Planck-Strasse 1, D-21502 Geesthacht, Germany
E-mail: nils.bergemann@hzg.de

b Pavia H2 Lab, C.S.G.I. & Dipartimento di Chimica, Sezione di Chimica Fisica, Universitá di Pavia, Viale Taramelli 16, I-27100 Pavia, Italy

c Department of Chemistry and NIS Centre, University of Torino, V. P. Giuria 7, I–10125 Torino, Italy

d Helmut Schmidt University, Mechanical Engineering, Holstenhofweg 85, D-22043 Hamburg, Germany

Abstract

The Ca(BH4)2–Mg2NiH4 system presented here is, to the best of our knowledge, the first described Ca(BH4)2-based hydride composite that reversibly transfers boron from the Ca-based compound(s) to the reaction partner. The ternary boride MgNi2.5B2 is formed upon dehydrogenation and the formation of Ca(BH4)2 upon rehydrogenation is confirmed.

Graphical abstract: Ca(BH4)2–Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C5CC09991A
Article type
Communication
Submitted
04 Dec 2015
Accepted
04 Mar 2016
First published
04 Mar 2016
This article is Open Access
Creative Commons BY license

Chem. Commun., 2016,52, 4836-4839

Author version available

Download author version (PDF)

Permissions

Request permissions

Ca(BH4)2–Mg2NiH4: on the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle

N. Bergemann, C. Pistidda, C. Milanese, T. Emmler, F. Karimi, A.-L. Chaudhary, M. R. Chierotti, T. Klassen and M. Dornheim, Chem. Commun., 2016, 52, 4836 DOI: 10.1039/C5CC09991A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements