Issue 65, 2015
From the journal:

Chemical Communications

Mechanical switching of magnetic interaction by tweezers-type complex†

Benjamin Doistau,ab   Jean-Louis Cantin,c   Lise-Marie Chamoreau,ab   Valérie Marvaud,ab   Bernold Hasenknopf*ab  and  Guillaume Vives*ab  

* Corresponding authors

a Sorbonne Universités, UPMC Univ Paris 06, UMR 8232, Institut Parisien de Chimie Moléculaire, 4 place Jussieu, Paris, France
E-mail: bernold.hasenknopf@upmc.fr, guillaume.vives@upmc.fr

b CNRS, UMR 8232, Institut Parisien de Chimie Moléculaire, 4 place Jussieu, Paris, France

c Sorbonne Universités, UPMC Univ Paris 06, INSP, 4 place Jussieu, Paris, France

Abstract

A control of the interaction between two spin centers was achieved by using a mechanical motion in a terpy(Cu–salphen)2 complex. Upon coordination a conformation change and switching from a paramagnetic to an antiferromagnetically coupled system was observed by EPR and SQUID measurements.

Graphical abstract: Mechanical switching of magnetic interaction by tweezers-type complex

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Article information

DOI
https://doi.org/10.1039/C5CC04980F
Article type
Communication
Submitted
16 Jun 2015
Accepted
07 Jul 2015
First published
08 Jul 2015
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 12916-12919

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Mechanical switching of magnetic interaction by tweezers-type complex

B. Doistau, J. Cantin, L. Chamoreau, V. Marvaud, B. Hasenknopf and G. Vives, Chem. Commun., 2015, 51, 12916 DOI: 10.1039/C5CC04980F

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