Issue 60, 2015

Tuning the depth of bowl-shaped phosphine hosts: capsule and pseudo-cage architectures in host–guest complexes with C60 fullerene

Abstract

Bowl-shaped phosphine molecules, whose bowl geometry can be controlled by a variation of the axial substituent, were synthesized, and used as host molecules to encapsulate C60. Host molecules with relatively shallow bowls formed a chiral capsule, while hosts with deeper bowls formed an achiral pseudo-cage.

Graphical abstract: Tuning the depth of bowl-shaped phosphine hosts: capsule and pseudo-cage architectures in host–guest complexes with C60 fullerene

Supplementary files

Article information

Article type
Communication
Submitted
21 May 2015
Accepted
16 Jun 2015
First published
16 Jun 2015

Chem. Commun., 2015,51, 12080-12083

Author version available

Tuning the depth of bowl-shaped phosphine hosts: capsule and pseudo-cage architectures in host–guest complexes with C60 fullerene

M. Yamamura, K. Sukegawa and T. Nabeshima, Chem. Commun., 2015, 51, 12080 DOI: 10.1039/C5CC04194E

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