Issue 16, 2014

Induced chirality in single walled carbon nanotube based self-assembly

Abstract

Chirality is an important determinant of the optical and electronic properties of single walled carbon nanotubes (SWNTs). Pristine zigzag SWNTs have been functionalized with lipids by a solid state functionalization process. Neither the lipids nor the SWNTs show a circular dichroism (CD) signal prior to functionalization. Upon functionalization, a change in the joint density of electronic states occurs which is reflected by a three-peak G′ band profile and the emergence of a CD signal. A molecular mechanism for the emergent CD signal associated with this lipid-specific self-assembly is described.

Graphical abstract: Induced chirality in single walled carbon nanotube based self-assembly

Supplementary files

Article information

Article type
Paper
Submitted
07 Jan 2014
Accepted
20 Jan 2014
First published
21 Jan 2014

J. Mater. Chem. A, 2014,2, 5759-5765

Induced chirality in single walled carbon nanotube based self-assembly

T. Bhattacharyya, S. Roy, P. Ray and A. Kr. Dasgupta, J. Mater. Chem. A, 2014, 2, 5759 DOI: 10.1039/C4TA00110A

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