Issue 23, 2014

Dynamic 2D manganese(ii) isonicotinate framework with reversible crystal-to-amorphous transformation and selective guest adsorption

Abstract

A 2D layered microporous isonicotinate-supported manganese(II) metal–organic framework was found to exhibit a reversible crystal-to-amorphous transformation upon the removal and uptake of certain guest molecules. Unsaturated metal centers, generated in the dynamic framework upon activation, were found to facilitate the selective adsorption of CO2versus N2.

Graphical abstract: Dynamic 2D manganese(ii) isonicotinate framework with reversible crystal-to-amorphous transformation and selective guest adsorption

Supplementary files

Article information

Article type
Communication
Submitted
28 Mar 2014
Accepted
25 Apr 2014
First published
25 Apr 2014

CrystEngComm, 2014,16, 4959-4962

Dynamic 2D manganese(II) isonicotinate framework with reversible crystal-to-amorphous transformation and selective guest adsorption

D. Matoga, B. Gil, W. Nitek, A. D. Todd and C. W. Bielawski, CrystEngComm, 2014, 16, 4959 DOI: 10.1039/C4CE00647J

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