Issue 21, 2015
From the journal:

Chemical Communications

Coordination-driven self-assembly of an iridium-cornered prismatic cage and encapsulation of three heteroguests in its large cavity†

Nem Singh,a   Jae-Ho Jo,a   Young Ho Song,a   Hyunuk Kim,b   Dongwook Kim,c   Myoung Soo Lahc  and  Ki-Whan Chi*a  

* Corresponding authors

a Department of Chemistry, University of Ulsan, Ulsan 680-749, Republic of Korea
E-mail: kwchi@ulsan.ac.kr

b Energy Materials Laboratory, Korea Institute of Energy Research, Daejeon 305-343, Republic of Korea

c Department of Chemistry, Ulsan National Institute of Science & Technology, Ulsan 689-805, Republic of Korea

Abstract

A hollow iridium-cornered prismatic cage was self-assembled without the assistance of any template. The cage was found to be capable of encapsulating heteroguest's triplet in its perfect sized cavity, producing the first demonstration of quintuple structure by an octahedral metal cornered prismatic cage.

Graphical abstract: Coordination-driven self-assembly of an iridium-cornered prismatic cage and encapsulation of three heteroguests in its large cavity

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Article information

DOI
https://doi.org/10.1039/C4CC09494H
Article type
Communication
Submitted
27 Nov 2014
Accepted
06 Feb 2015
First published
06 Feb 2015

Chem. Commun., 2015,51, 4492-4495

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Coordination-driven self-assembly of an iridium-cornered prismatic cage and encapsulation of three heteroguests in its large cavity

N. Singh, J. Jo, Y. H. Song, H. Kim, D. Kim, M. S. Lah and K. Chi, Chem. Commun., 2015, 51, 4492 DOI: 10.1039/C4CC09494H

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