Issue 93, 2014
From the journal:

Chemical Communications

Doubly N-confused isophlorin: synthesis, structure and copper coordination†

Jiaying Yan,ab   Makoto Takakusaki,a   Yufeng Yang,a   Shigeki Mori,c   Bao Zhang,b   Yaqing Feng,*b   Masatoshi Ishidaa  and  Hiroyuki Furuta*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Graduate School of Engineering, International Research Center for Molecular Systems and Education Center for Global Leaders in Molecular Systems for Devices, Kyushu University, Fukuoka 819-0395, Japan
E-mail: hfuruta@cstf.kyushu-u.ac.jp

b School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, P.R. China
E-mail: yqfeng@tju.edu.cn

c Integrated Center for Science, Ehime University, Matsuyama 790-8577, Japan

Abstract

A novel doubly N-confused isophlorin (2) was prepared by the nucleophilic ring-opening reaction of N-confused, N-fused porphyrin (1) with benzenethiol. The structure, redox property and copper coordination ability of isophlorin 2 were investigated by various spectroscopic methods and theoretical calculations.

Graphical abstract: Doubly N-confused isophlorin: synthesis, structure and copper coordination

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Article information

DOI
https://doi.org/10.1039/C4CC06259K
Article type
Communication
Submitted
09 Aug 2014
Accepted
23 Sep 2014
First published
23 Sep 2014

Chem. Commun., 2014,50, 14593-14596

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Doubly N-confused isophlorin: synthesis, structure and copper coordination

J. Yan, M. Takakusaki, Y. Yang, S. Mori, B. Zhang, Y. Feng, M. Ishida and H. Furuta, Chem. Commun., 2014, 50, 14593 DOI: 10.1039/C4CC06259K

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