Issue 66, 2014
From the journal:

Chemical Communications

Rich diversity of single-ion magnet features in the linear OCuIIIO− ion confined in the hexagonal channels of alkaline-earth phosphate apatites†

Pavel E. Kazin,*a   Mikhail A. Zykin,b   Walter Schnelle,c   Claudia Felserc  and  Martin Jansencd  

* Corresponding authors

a Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia
E-mail: kazin@inorg.chem.msu.ru
Fax: +7 495 9390998
Tel: +7 495 9393440

b Department of Materials Science, Lomonosov Moscow State University, 119991 Moscow, Russia

c Max Planck Institute for Chemical Physics of Solids, Nöthnitzer Straße 40, 01187 Dresden, Germany

d Max Planck Institute for Solid State Research, Heisenbergstrasse 1, 70569 Stuttgart, Germany

Abstract

Following our recent discovery of slow spin relaxation in the unique [OCuIIIO]− anion located in the apatite-type pigment A10(PO4)6(CuxOH1−x−y)2, where A = Sr, we present the magnetic behavior of this anion for the cases of A = Ca and Ba, which provides evidence for a cation field impact on the properties of a single-ion magnet molecular anion.

Graphical abstract: Rich diversity of single-ion magnet features in the linear OCuIIIO− ion confined in the hexagonal channels of alkaline-earth phosphate apatites

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Article information

DOI
https://doi.org/10.1039/C4CC03966A
Article type
Communication
Submitted
23 May 2014
Accepted
13 Jun 2014
First published
13 Jun 2014

Chem. Commun., 2014,50, 9325-9328

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Rich diversity of single-ion magnet features in the linear OCuIIIO− ion confined in the hexagonal channels of alkaline-earth phosphate apatites

P. E. Kazin, M. A. Zykin, W. Schnelle, C. Felser and M. Jansen, Chem. Commun., 2014, 50, 9325 DOI: 10.1039/C4CC03966A

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