Issue 6, 2014

A layer-built rechargeable lithium ribbon-type battery for high energy density textile battery applications

Abstract

We designed a novel layer-built rechargeable lithium ribbon-type battery intended for textile or cloth based applications. The ribbon-type battery, 2.4 mm (or 1 mm) wide and 10 cm long, is composed of a double layer LiFePO4 cathode and an amorphous silicon nanofilm. The double layer LiFePO4 and amorphous silicon electrodes were prepared using the doctor blade method and a vertical deposition technique, respectively. The structure and morphology of the LiFePO4 and the silicon thin film were characterized by Rietveld refinement, SEM and TEM. At room temperature the ribbon-type battery exhibited an initial discharge capacity of 166.4 and 132.7 mA h g−1 at 0.5 and 1 C-rate, respectively. A reasonably good cycling performance and high coulombic efficiency under the high current density of 1 C-rate could be obtained with the Si/LiFePO4 ribbon-type battery. Also, a high volumetric capacity of 336 mA h cm−3 at 0.5 C-rate was achieved, which makes the ribbon-type battery suitable for practical use.

Graphical abstract: A layer-built rechargeable lithium ribbon-type battery for high energy density textile battery applications

Supplementary files

Article information

Article type
Paper
Submitted
18 Oct 2013
Accepted
07 Nov 2013
First published
13 Dec 2013

J. Mater. Chem. A, 2014,2, 1774-1780

A layer-built rechargeable lithium ribbon-type battery for high energy density textile battery applications

J. Kim, J. Scheers, H. Ryu, J. Ahn, T. Nam, K. Kim, H. Ahn, G. Cho and P. Jacobsson, J. Mater. Chem. A, 2014, 2, 1774 DOI: 10.1039/C3TA14197G

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