Issue 1, 2014
From the journal:

Dalton Transactions

Impact of high π-density on the coordination properties of π-excess aromatic neutral σ2P ligands – P(π)-donor bonds to Ag+ and HgCl2†

Mohammed Ghalib,a   László Könczöl,b   László Nyulászi,*b   Peter G. Jones,*c   Gottfried J. Palmd  and  Joachim W. Heinicke*a  

* Corresponding authors

a Institut für Biochemie (Anorganische Chemie), E.-M.-A.-Universität Greifswald, 17487 Greifswald, Germany
E-mail: heinicke@uni-greifswald.de
Fax: +49-3834-864377
Tel: +49-3834-864318

b Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, Hungary

c Institut für Anorganische und Analytische Chemie, Techn. Universität Braunschweig, D-38023 Braunschweig, Germany

d Institut für Biochemie (Molekulare Strukturbiologie), E.-M.-A.-Universität Greifswald, 17487 Greifswald, Germany

Abstract

Unprecedented coordination types of non-zerovalent d10 transition metals (AgX, HgCl2) by π-excess aromatic P[double bond, length as m-dash]C ligands involving P(π)-donor bond contributions were detected by structural and quantum chemical studies.

Graphical abstract: Impact of high π-density on the coordination properties of π-excess aromatic neutral σ2P ligands – P(π)-donor bonds to Ag+ and HgCl2

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Article information

DOI
https://doi.org/10.1039/C3DT52909F
Article type
Communication
Submitted
15 Oct 2013
Accepted
17 Oct 2013
First published
22 Oct 2013
This article is Open Access
Creative Commons BY license

Dalton Trans., 2014,43, 51-54

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Impact of high π-density on the coordination properties of π-excess aromatic neutral σ2P ligands – P(π)-donor bonds to Ag+ and HgCl2

M. Ghalib, L. Könczöl, L. Nyulászi, P. G. Jones, G. J. Palm and J. W. Heinicke, Dalton Trans., 2014, 43, 51 DOI: 10.1039/C3DT52909F

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