Issue 27, 2013

H/F isosteric substitution to attest different equi-energetic molecular conformations in crystals

Abstract

The sequential replacement of aromatic H-atoms by F-atoms in 1,6-bis(phenylcarbonate) hexa-2,4-diyne allows access to its possible iso-energetic “syn”, “gauche” and “anti” conformations.

Graphical abstract: H/F isosteric substitution to attest different equi-energetic molecular conformations in crystals

Supplementary files

Article information

Article type
Communication
Submitted
26 Feb 2013
Accepted
09 May 2013
First published
10 May 2013

CrystEngComm, 2013,15, 5403-5406

H/F isosteric substitution to attest different equi-energetic molecular conformations in crystals

A. G. Dikundwar, Ch. Venkateswarlu, R. N. Chandrakala, S. Chandrasekaran and T. N. G. Row, CrystEngComm, 2013, 15, 5403 DOI: 10.1039/C3CE40697K

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