Issue 91, 2013
From the journal:

Chemical Communications

Synthesis, characterisation, and oxygen atom transfer reactions involving the first gold(i)-alkylperoxo complexes†

Alba Collado,a   Adrián Gómez-Suárez,a   Yoshihiro Oonishi,a   Alexandra M. Z. Slawina  and  Steven P. Nolan*a  

* Corresponding authors

a EaStCHEM School of Chemistry, University of St. Andrews, St. Andrews, UK
E-mail: snolan@st-andrews.ac.uk
Fax: +44 (0)1334463808
Tel: +44 (0)1334463763

Abstract

The synthesis of a new class of organogold species containing a peroxo moiety is reported. Complexes [Au(IPr)(OOtBu)] and [Au(SIPr)(OOtBu)] have been synthesised via a straightforward methodology using the parent gold(I) hydroxide complexes as synthons. These complexes have been successfully used in oxygen-transfer reactions to triphenylphosphine.

Graphical abstract: Synthesis, characterisation, and oxygen atom transfer reactions involving the first gold(i)-alkylperoxo complexes

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Article information

DOI
https://doi.org/10.1039/C3CC47030J
Article type
Communication
Submitted
13 Sep 2013
Accepted
27 Sep 2013
First published
30 Sep 2013

Chem. Commun., 2013,49, 10745-10747

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Synthesis, characterisation, and oxygen atom transfer reactions involving the first gold(I)-alkylperoxo complexes

A. Collado, A. Gómez-Suárez, Y. Oonishi, A. M. Z. Slawin and S. P. Nolan, Chem. Commun., 2013, 49, 10745 DOI: 10.1039/C3CC47030J

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