Issue 6, 1995
From the journal:

Journal of the Chemical Society, Chemical Communications

First resolution of a linear chelating tetra(tertiary phosphine): resolution and absolute configurations of enantiomers of (R*,R*)-(±)-1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetraphosphadecane

Anthea L. Airey,   Gerhard F. Swiegers,   Anthony C. Willis  and  S. Bruce Wild  

Abstract

The important and commercially available linear tetra(tertiary phosphine)(R*,R*)-(±)/(R*,S*)-Ph2PCH2CH2P(Ph)CH2CH2P(Ph)CH2CH2PPh2 has been separated into diastereoisomers and the (R*,R*)-(±)-diastereoisomer resolved by the method of metal complexation giving the first optically active tetra(tertiary phosphine).

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Article information

DOI
https://doi.org/10.1039/C39950000693
Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 693-694

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First resolution of a linear chelating tetra(tertiary phosphine): resolution and absolute configurations of enantiomers of (R*,R*)-(±)-1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetraphosphadecane

A. L. Airey, G. F. Swiegers, A. C. Willis and S. B. Wild, J. Chem. Soc., Chem. Commun., 1995, 693 DOI: 10.1039/C39950000693

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