SCHEDULED MAINTENANCE
By reaction with propene sulfide, one or two sulfur atoms are added to the tetrahedral cluster cation [Pt3{Re(CO)3}(µ-dppm)3]+1(dppm = Ph2PCH2PPh2), to give [Pt3{Re(CO)3}Sn(µ-dppm)3]+(n= 1, 2; n= 2, 3); the reactions provide an interesting model for sulfidation of heterogeneous Pt–Re catalysts.
L. Hao, J. Xiao, J. J. Vittal and R. J. Puddephatt, J. Chem. Soc., Chem. Commun., 1994, 2183 DOI: 10.1039/C39940002183
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