Issue 20, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Bis[η5-(2,4-dimethyl-1-oxapentadienyl)]ruthenium(II): the first homoleptic open ruthenocenes with non-hydrocarbon ligands

Thomas Schmidt  and  Richard Goddard  

Abstract

The new stereoisomeric bis(1-oxapentadienyl)ruthenium(II) complexes 3a and b are obtained by reductive dehalogenation of RuCl3·aq. in the presence of 4-methylbuten-2-ones; they have been characterized spectroscopically and their crystal structures have been determined, showing a distorted syn-gauche and the unusual anti-eclipsed arrangement of the ligands, respectively.

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Article information

DOI
https://doi.org/10.1039/C39910001427
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 1427-1429

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Bis[η5-(2,4-dimethyl-1-oxapentadienyl)]ruthenium(II): the first homoleptic open ruthenocenes with non-hydrocarbon ligands

T. Schmidt and R. Goddard, J. Chem. Soc., Chem. Commun., 1991, 1427 DOI: 10.1039/C39910001427

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