Issue 22, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

A near-planar pentadentate silver(I) complex; the crystal and molecular structure of (2,2′ : 6′,2″ : 6″,2‴ : 6‴,2â�—-quinquepyridine)silver(I) hexafluorophosphate

Edwin C. Constable,   Michael G. B. Drew,   G. Forsyth  and  Michael D. Ward  

Abstract

The complex [AgL1][PF6](L1= 2,2′ :6′,2″ :6″,2‴ : 6‴,2â�—-quinquepyridine) has been prepared and structurally characterised; in contrast to the double helical binuclear complexes formed with first row transition metal ions, the title complex is mononuclear, with a near-planar arrangement of the ligand about the metal, and the cation exhibits weak π-interactions with adjacent cations, but there is no direct Ag–Ag interaction.

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Article information

DOI
https://doi.org/10.1039/C39880001450
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1450-1451

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A near-planar pentadentate silver(I) complex; the crystal and molecular structure of (2,2′ : 6′,2″ : 6″,2‴ : 6‴,2â�—-quinquepyridine)silver(I) hexafluorophosphate

E. C. Constable, M. G. B. Drew, G. Forsyth and M. D. Ward, J. Chem. Soc., Chem. Commun., 1988, 1450 DOI: 10.1039/C39880001450

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