Issue 8, 1987

Stereoselective intramolecular nitrile oxide cycloaddition to chiral allyl ethers

Abstract

Intramolecular nitrile oxide cycloaddition reactions on (Z)- and (E)-chiral allyl ethers occur with poor to good stereoselectivity (diastereoisomeric ratios up to 86: 14), which depends on the double bond configuration as well as on steric and stereoelectronic effects.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 529-530

Stereoselective intramolecular nitrile oxide cycloaddition to chiral allyl ethers

R. Annunziata, M. Cinquini, F. Cozzi and L. Raimondi, J. Chem. Soc., Chem. Commun., 1987, 529 DOI: 10.1039/C39870000529

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