Issue 15, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Ethene chlorination and oxidative coupling over supported mono- and bi-metallic chloride catalysts

Keith Rollins  and  Paul A. Sermon  

Abstract

Temperature-programmed reduction of metal chlorides upon silica, alumina, and titania supports using ethene produces chloroethene and 1,2-dichloroethane, together with rather unexpectedly, 1,1-dichloroethane and benzene in yields which differ from one metal chloride to another; results suggest the involvement of novel ‥ H/Cl ‥ exchange and oxidative-coupling reactions and also suggest that this technique of ethene titration may be of value in characterising the active sites in chloride catalysts and catalytic precursors.

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Article information

DOI
https://doi.org/10.1039/C39860001171
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1171-1173

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Ethene chlorination and oxidative coupling over supported mono- and bi-metallic chloride catalysts

K. Rollins and P. A. Sermon, J. Chem. Soc., Chem. Commun., 1986, 1171 DOI: 10.1039/C39860001171

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