Issue 20, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and X-ray crystal structure of [Mo(CO2)2(PMe3)3(CNPri)]: the first structurally characterized bis(carbon dioxide) adduct of a transition metal

Rafael Alvarez,   Ernesto Carmona,   Enrique Gutierrez-Puebla,   José M. Marín,   Angeles Monge  and  Manuel L. Poveda  

Abstract

The reaction of trans-[Mo(CO2)2(PMe3)4] with isocyanides yields the new bis(carbon dioxide) complexes trans, mer-[Mo(CO2)2(CNR)(PMe3)3], (R = Me, Pri, or But); the structure of the isopropyl derivative [Mo(CO2)2(CNPri)(PMe3)3] has been determined by X-ray crystallography.

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Article information

DOI
https://doi.org/10.1039/C39840001326
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1326-1327

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Synthesis and X-ray crystal structure of [Mo(CO2)2(PMe3)3(CNPri)]: the first structurally characterized bis(carbon dioxide) adduct of a transition metal

R. Alvarez, E. Carmona, E. Gutierrez-Puebla, J. M. Marín, A. Monge and M. L. Poveda, J. Chem. Soc., Chem. Commun., 1984, 1326 DOI: 10.1039/C39840001326

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