Azobenzenes are shown for the first time to exhibit substantial Li+ and Na+ cation effects on their electrochemical behaviour, and although K+ does not interact with Ar–N![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
N–Ar, or its reduced form, a srong interaction is observed when K+ is bound as a cryptate complex.
D. A. Gustowski, V. J. Gatto, A. Kaifer, L. Echegoyen, R. E. Godt and G. W. Gokel, J. Chem. Soc., Chem. Commun., 1984, 923 DOI: 10.1039/C39840000923
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