Issue 11, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Steric and electronic effects on the chemistry of molybdenum octahedrally co-ordinated by six nitrogen atoms. The molecular structure of [Mo{HB(3,5-Me2C3N2H)3}(NO)(pyrollide)2]

Najat Al Obaidi,   Katherine P. Brown,   Anthony J. Edwards,   Susan A. Hollins,   Christopher J. Jones,   Jon A. McCleverty  and  Bryan D. Neaves  

Abstract

[Mo{HB(3,5-Me2C3N2H)3}(No)I2] reacts with the nitrogen heterocycles Z to give [Mo{HB(3,5-Me2C3N2H)3}(NO)Z2]+, where Z = pyridine, imidazole, N-methylimidazole, or pyrazole, with monosidium organoamides to give [Mo{HB(3,5-Me2C3N2H)3}(NO)Y2] where Y = NHEt–, NHPh–, p-NHC6H4Me–, or pyrollide, and with moist tetrahydrofuran to give [Mo{HB(3,5-Me2C3N2H)3}(NO)I{O[CH2]4I}]; the molecular structure of [Mo{HB(3, 5-Me2C3N2H)3}(NO)-(pyrollide)2] has been determined.

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Article information

DOI
https://doi.org/10.1039/C39840000690
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 690-692

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Steric and electronic effects on the chemistry of molybdenum octahedrally co-ordinated by six nitrogen atoms. The molecular structure of [Mo{HB(3,5-Me2C3N2H)3}(NO)(pyrollide)2]

N. A. Obaidi, K. P. Brown, A. J. Edwards, S. A. Hollins, C. J. Jones, J. A. McCleverty and B. D. Neaves, J. Chem. Soc., Chem. Commun., 1984, 690 DOI: 10.1039/C39840000690

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