Chiral dioxirane intermediates, which are formed in the reaction of potassium peroxomonosulphate with chiral ketones, allow the epoxidation of simple pro-chiral olefins to the corresponding epoxides to be carried out with enantiomeric excesses in the range 9–12.5%.
R. Curci, M. Fiorentino and M. R. Serio, J. Chem. Soc., Chem. Commun., 1984, 155 DOI: 10.1039/C39840000155
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