Issue 4, 1982

Insertion of carbon dioxide and of unsaturated carbon compounds into the platinum–nitrogen bond: the X-ray crystal structure of Pt{ON(Ph)C(O)O}(PPh3)2

Abstract

Pt(PhNo)(PPh3)2 reacts with unsaturated carbon compounds such as carbon dioxide, carbon disulphide, alkenes, and dimethyl acetuylenedicarboxylate to give 1:1 adducts; X-ray studies on the adduct formed with carbon dioxide, [graphic omitted]}(PPh3)2, show that the entering molecule is inserted into the platinum–nitrogen bond of the η2-bonded nitroso ligand.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 265-266

Insertion of carbon dioxide and of unsaturated carbon compounds into the platinum–nitrogen bond: the X-ray crystal structure of Pt{ON(Ph)C(O)O}(PPh3)2

P. L. Bellon, S. Cenini, F. Demartin, M. Pizzotti and F. Porta, J. Chem. Soc., Chem. Commun., 1982, 265 DOI: 10.1039/C39820000265

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