The cyclic carbamoyl complexes [(CO)4-[graphic omitted]R2] undergo both thermal and photochemical decarbonylation to form novel π-diazaallyl complexes (CO)4[graphic omitted]R2; attempts to reverse the process by treatment with CO at high pressures and temperatures gave only [(CO)5MnN(R2)C(R1):NR2]; no evidence was obtained for insertion into the Mn–N bonds.
T. Inglis, M. Kilner and T. Reynoldson, J. Chem. Soc., Chem. Commun., 1972, 774 DOI: 10.1039/C39720000774
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