Issue 5, 2013
From the journal:

Polymer Chemistry

Mono- and di-cyclocarbonate telechelic polyolefins synthesized from ROMP using glycerol carbonate derivatives as chain-transfer agents†

Liana Annunziata,a   Stéphane Fouquay,b   Guillaume Michaud,c   Frédéric Simon,c   Sophie M. Guillaume*a  and  Jean-François Carpentier*a  

* Corresponding authors

a Organometallics: Materials and Catalysis, UMR 6226 Institut Sciences Chimiques CNRS-Université de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex, France
E-mail: jean-francois.carpentier@univ-rennes1.fr, sophie.guillaume@univ-rennes1.fr
Tel: +33 223235950

b BOSTIK S.A. 16-32, rue H. Regnault, 92902 Paris La Défense, France

c BOSTIK CRD, Route de Bailly, 60771 Ribécourt Cedex, France

Abstract

The ring-opening metathesis polymerization (ROMP) of cyclooctene (COE) has been achieved with Grubbs 2nd generation ruthenium catalyst in the presence of vinyl or acryloyl derivatives of glycerol carbonate. Such asymmetric chain-transfer agents enabled the synthesis in high yields of α-cyclocarbonate,ω-vinyl-poly(cyclooctene) (PCOE) and, more rewardingly, of the highly valuable α,ω-dicyclocarbonate telechelic PCOE.

Graphical abstract: Mono- and di-cyclocarbonate telechelic polyolefins synthesized from ROMP using glycerol carbonate derivatives as chain-transfer agents

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2PY21141F
Article type
Communication
Submitted
22 Dec 2012
Accepted
05 Jan 2013
First published
08 Jan 2013

Polym. Chem., 2013,4, 1313-1316

Permissions

Request permissions

Mono- and di-cyclocarbonate telechelic polyolefins synthesized from ROMP using glycerol carbonate derivatives as chain-transfer agents

L. Annunziata, S. Fouquay, G. Michaud, F. Simon, S. M. Guillaume and J. Carpentier, Polym. Chem., 2013, 4, 1313 DOI: 10.1039/C2PY21141F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements