Issue 3, 2012
From the journal:

Polymer Chemistry

Iron-based pre-catalyst supported on polyformamidine for C–C bond formation

Stephan Enthaler,*a   Sebastian Krackl,ab   Jan Dirk Epping,b   Björn Eckhardt,ac   Steffen M. Weidnerd  and  Anna Fischera  

* Corresponding authors

a Technische Universität Berlin, Department of Chemistry, Cluster of Excellence “Unifying Concepts in Catalysis”, Straße des 17. Juni 135/C2, Berlin, Germany
E-mail: stephan.enthaler@tu-berlin.de
Fax: +493031429732
Tel: +493031422039

b Technische Universität Berlin, Department of Chemistry, Metalorganics and Inorganic Materials, Technische Universität Berlin, Straße des 17. Juni 135/C2, Berlin, Germany

c Technische Universität Berlin, Department of Chemistry, Straße des 17. Juni 124/TC03, Berlin, Germany

d Bundesanstalt für Materialforschung und -prüfung (BAM), Federal Institute for Materials Research and Testing, Richard-Willstätter-Straße 11, Berlin, Germany

Abstract

In the present study the incorporation of iron into an organic polymer, composed of formamidine subunits [R–N[double bond, length as m-dash]C(H)–NH–R], has been examined. The catalytic ability of the recyclable material was investigated in the iron-catalyzed formation of C–C bonds. After optimization of the reaction conditions, excellent yields and chemoselectivities were feasible.

Graphical abstract: Iron-based pre-catalyst supported on polyformamidine for C–C bond formation

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Article information

DOI
https://doi.org/10.1039/C2PY00540A
Article type
Paper
Submitted
10 Nov 2011
Accepted
30 Dec 2011
First published
20 Jan 2012

Polym. Chem., 2012,3, 751-756

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Iron-based pre-catalyst supported on polyformamidine for C–C bond formation

S. Enthaler, S. Krackl, J. D. Epping, B. Eckhardt, S. M. Weidner and A. Fischer, Polym. Chem., 2012, 3, 751 DOI: 10.1039/C2PY00540A

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