Issue 13, 2013
From the journal:

Dalton Transactions

Ferromagnetic interactions through double hydrogen bonding bridges in manganese(ii) coordination polymers†

Kun Wang,a   Yan-Qin Wang,a   Xiu-Mei Zhanga  and  En-Qing Gao*a  

* Corresponding authors

a Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, P. R. China
E-mail: eqgao@chem.ecnu.edu.cn
Fax: +86-21-62233404
Tel: +86-21-62233404

Abstract

Three isostructural Mn(II) compounds with a zwitterionic dicarboxylate ligand and different pseudohalides were synthesized, and then structurally and magnetically characterized. They are formulated as [Mn(L)(X)2(H2O)2]n [X = N3− (1), NCO− (2), NCS− (3), L = 1,4-bis(4-carboxylato-1-pyridinium)butane]. In these compounds, adjacent Mn(II) ions are connected into coordination chains by long zwitterionic linkers and into hydrogen-bonded chains by short double O–H⋯N bridges involving coordinated water and pseudohalide ligands. Magnetic studies revealed for the first time that the double hydrogen bridges induce ferromagnetic coupling between the Mn(II) ions.

Graphical abstract: Ferromagnetic interactions through double hydrogen bonding bridges in manganese(ii) coordination polymers

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2DT32826G
Article type
Paper
Submitted
27 Nov 2012
Accepted
14 Dec 2012
First published
17 Dec 2012

Dalton Trans., 2013,42, 4533-4538

Permissions

Request permissions

Ferromagnetic interactions through double hydrogen bonding bridges in manganese(II) coordination polymers

K. Wang, Y. Wang, X. Zhang and E. Gao, Dalton Trans., 2013, 42, 4533 DOI: 10.1039/C2DT32826G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements