Issue 6, 2013

A highly efficient light capturing 2D (nanosheet)–1D (nanorod) combined hierarchical ZnO nanostructure for efficient quantum dot sensitized solar cells

Abstract

A novel hierarchical ZnO nanostructure array composed of nanosheet branched (NB) ZnO nanorods (NRs) has been fabricated using a two-step solution reaction. The obtained nanosheet branched (NB) ZnO nanorods (NRs) exhibited considerably enhanced light capturing compared with ZnO thin films and ZnO nanorods. This combined 2D (nanosheet) and 1D (nanorod) hierarchical structure has significant potential as an efficient photoanode for quantum dot-sensitized solar cells (QDSSCs) because the nanosheets provide a large surface area for quantum dot loading and the nanorods present pathways for fast charge transfer. The CdSe/CdS co-sensitized QDSSCs using these nanosheet branched (NB) ZnO nanorods (NRs) as a photoanode exhibit a highly enhanced solar-energy conversion efficiency of 4.4% under conditions of 1 sun illumination.

Graphical abstract: A highly efficient light capturing 2D (nanosheet)–1D (nanorod) combined hierarchical ZnO nanostructure for efficient quantum dot sensitized solar cells

Article information

Article type
Paper
Submitted
14 Nov 2012
Accepted
03 Dec 2012
First published
06 Dec 2012

Phys. Chem. Chem. Phys., 2013,15, 2109-2116

A highly efficient light capturing 2D (nanosheet)–1D (nanorod) combined hierarchical ZnO nanostructure for efficient quantum dot sensitized solar cells

H. Kim and K. Yong, Phys. Chem. Chem. Phys., 2013, 15, 2109 DOI: 10.1039/C2CP44045H

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