Issue 9, 2011

A flexible, unified radical-based approach to polycyclic structures

Abstract

Cis- and trans-decalins, trans-perhydroazulenes, and [5.3.1]-bicyclo-undecanone scaffolds can be readily constructed starting from unsaturated ketones and using the degenerative xanthate transfer technology to accomplish unusual and otherwise difficult radical cyclisations.

Graphical abstract: A flexible, unified radical-based approach to polycyclic structures

Supplementary files

Article information

Article type
Paper
Submitted
05 Jan 2011
Accepted
09 Feb 2011
First published
10 Feb 2011

Org. Biomol. Chem., 2011,9, 3396-3404

A flexible, unified radical-based approach to polycyclic structures

R. Heng and S. Z. Zard, Org. Biomol. Chem., 2011, 9, 3396 DOI: 10.1039/C1OB00024A

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