Issue 28, 2011
From the journal:

Dalton Transactions

Synthesis of dimeric ReI amino acid conjugate complexes†

Hira Qayyum,a   Richard S. Herrick*b  and  Christopher J. Ziegler*a  

* Corresponding authors

a Department of Chemistry, University of Akron, Akron, USA
E-mail: ziegler@uakron.edu
Fax: +1 330-972-7370
Tel: +1 330-972-2531

b Department of Chemistry, College of the Holy Cross, Worcester, USA
E-mail: rherrick@holycross.edu
Fax: +1 508-793-3530
Tel: +1 508-793-2490

Abstract

The aqueous one-step reaction of Re(CO)3(H2O)3+ with pyridine-2-carboxyaldehyde and glycine or alanine produces a new class of cyclic dimeric products. The ligands of the chiral C2-symmetric products are bound via the diimine at one rhenium centre and via the pendant carboxylate to a second rhenium center.

Graphical abstract: Synthesis of dimeric ReI amino acid conjugate complexes

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Article information

DOI
https://doi.org/10.1039/C1DT10665A
Article type
Paper
Submitted
14 Apr 2011
Accepted
06 May 2011
First published
21 Jun 2011

Dalton Trans., 2011,40, 7442-7445

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Synthesis of dimeric ReI amino acid conjugate complexes

H. Qayyum, R. S. Herrick and C. J. Ziegler, Dalton Trans., 2011, 40, 7442 DOI: 10.1039/C1DT10665A

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