Issue 29, 2011
From the journal:

Chemical Communications

A versatile palladium catalyst system for Suzuki–Miyaura coupling of alkenyl tosylates and mesylates†

Pui Yu Wong,a   Wing Kin Chow,a   Kin Ho Chung,a   Chau Ming So,a   Chak Po Laua  and  Fuk Yee Kwong*a  

* Corresponding authors

a State Key Laboratory of Chirosciences and Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Kowloon, Hong Kong
E-mail: bcfyk@inet.polyu.edu.hk

Abstract

A general and effective palladium system for Suzuki–Miyaura coupling of alkenyl electrophiles under mild reaction conditions is reported. With the Pd(OAc)2/CM-phos system, a variety of alkenyl tosylates are coupled well with ArB(OH)2. Moreover, the first successful examples of using alkenyl mesylates in alkenylation are also described.

Graphical abstract: A versatile palladium catalyst system for Suzuki–Miyaura coupling of alkenyl tosylates and mesylates

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Article information

DOI
https://doi.org/10.1039/C1CC12240A
Article type
Communication
Submitted
18 Apr 2011
Accepted
25 May 2011
First published
17 Jun 2011

Chem. Commun., 2011,47, 8328-8330

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A versatile palladium catalyst system for Suzuki–Miyaura coupling of alkenyl tosylates and mesylates

P. Y. Wong, W. K. Chow, K. H. Chung, C. M. So, C. P. Lau and F. Y. Kwong, Chem. Commun., 2011, 47, 8328 DOI: 10.1039/C1CC12240A

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