Issue 35, 2010
From the journal:

Dalton Transactions

Cobalt complexes as the building blocks: {Co3+–Zn2+} heterobimetallic networks and their properties†‡

Amit Pratap Singh,a   Afsar Alia  and  Rajeev Gupta*a  

* Corresponding authors

a Department of Chemistry, University of Delhi, INDIA
E-mail: rgupta@chemistry.du.ac.in
Fax: 91-11-2766 6605
Tel: 91-11-27666646

Abstract

Two {Co3+–Zn2+} heterobimetallic coordination networks have been synthesized utilizing Co3+ complex as the building blocks. The structural studies reveal 2D sheet-like networks where the Co3+ containing building blocks are connected through Zn2+ ions. Two different building blocks generate two unique networks as evidenced by the crystallographic studies and other properties. These networks are shown to catalyze Lewis metal ion assisted Strecker reaction in heterogeneous manner.

Graphical abstract: Cobalt complexes as the building blocks: {Co3+–Zn2+} heterobimetallic networks and their properties

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Article information

DOI
https://doi.org/10.1039/C0DT00511H
Article type
Communication
Submitted
20 May 2010
Accepted
12 Jul 2010
First published
04 Aug 2010

Dalton Trans., 2010,39, 8135-8138

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Cobalt complexes as the building blocks: {Co3+–Zn2+} heterobimetallic networks and their properties

A. P. Singh, A. Ali and R. Gupta, Dalton Trans., 2010, 39, 8135 DOI: 10.1039/C0DT00511H

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