Issue 28, 2010
From the journal:

Chemical Communications

Unsaturated β-ketoesters as versatile electrophiles in organocatalysis†

Susy Piovesana,a   Daniele M. Scarpino Schietroma,a   Ludovico G. Tulli,a   Mattia R. Monacoa  and  Marco Bella*a  

* Corresponding authors

a Dipartimento di Chimica, “Sapienza” University of Roma and Istituto di Chimica Biomolecolare del CNR, P.le Aldo Moro 5, 00185 Roma, Italy
E-mail: Marco.Bella@uniroma1.it
Fax: +39 06 490631

Abstract

β-Ketoesters, which have widely been employed as nucleophiles, are also useful electrophiles in organocatalytic quinine mediated cascade reactions, leading to the formation of products bearing multiple stereocenters in high stereoselectivity.

Graphical abstract: Unsaturated β-ketoesters as versatile electrophiles in organocatalysis

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Article information

DOI
https://doi.org/10.1039/C003296D
Article type
Communication
Submitted
17 Feb 2010
Accepted
20 May 2010
First published
07 Jun 2010

Chem. Commun., 2010,46, 5160-5162

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Unsaturated β-ketoesters as versatile electrophiles in organocatalysis

S. Piovesana, D. M. S. Schietroma, L. G. Tulli, M. R. Monaco and M. Bella, Chem. Commun., 2010, 46, 5160 DOI: 10.1039/C003296D

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