Issue 13, 2010
From the journal:

Dalton Transactions

Gallium–gallium bonds as efficient templates for the generation of a large cage containing twelve gallium atoms†

Werner Uhl,*a   Matthias Voß,a   Marcus Layha  and  Friedhelm Rogela  

* Corresponding authors

a Institut für Anorganische und Analytische Chemie der Universität Münster, Corrensstraße 30, Münster, Germany
E-mail: uhlw@uni-muenster.de
Fax: +49 251 36660

Abstract

Treatment of the digallium compound R2Ga–GaR21 [R = CH(SiMe3)2] with benzotriazol-5-carboxylic acid afforded a large cage-like compound in which six Ga–Ga bonds are bridged by six trifunctional ligands. The central cavity encapsulated a THF molecule which cannot be removed in vacuo and does not show exchange with a large excess of the solvent.

Graphical abstract: Gallium–gallium bonds as efficient templates for the generation of a large cage containing twelve gallium atoms

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Article information

DOI
https://doi.org/10.1039/C001032B
Article type
Communication
Submitted
20 Oct 2009
Accepted
30 Jan 2010
First published
09 Feb 2010

Dalton Trans., 2010,39, 3160-3162

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Gallium–gallium bonds as efficient templates for the generation of a large cage containing twelve gallium atoms

W. Uhl, M. Voß, M. Layh and F. Rogel, Dalton Trans., 2010, 39, 3160 DOI: 10.1039/C001032B

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