Issue 16, 2010
From the journal:

Chemical Communications

Easy oxidatively induced silicon–carbon bond activation in organoplatinum chemistry†

Muhieddine Safa,a   Michael C. Jenningsa  and  Richard J. Puddephatt*a  

* Corresponding authors

a Department of Chemistry, University of Western Ontario, London, Canada
E-mail: pudd@uwo.ca

Abstract

The oxidation of the complex [PtMe2(bps)], bps = bis(2-pyridyl)dimethylsilane, by oxygen, hydrogen peroxide or dibenzoyl peroxide in the presence of water or alcohol gives the complex cation, [PtMe3(κ3-N,N,O-HOSiMe(2-C5H4N)2)]+, in a reaction involving easy cleavage of a methylsilicon bond.

Graphical abstract: Easy oxidatively induced silicon–carbon bond activation in organoplatinum chemistry

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Article information

DOI
https://doi.org/10.1039/B927248H
Article type
Communication
Submitted
24 Dec 2009
Accepted
19 Feb 2010
First published
04 Mar 2010

Chem. Commun., 2010,46, 2811-2813

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Easy oxidatively induced silicon–carbon bond activation in organoplatinum chemistry

M. Safa, M. C. Jennings and R. J. Puddephatt, Chem. Commun., 2010, 46, 2811 DOI: 10.1039/B927248H

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