Issue 7, 2010
From the journal:

Dalton Transactions

Highly luminescent bis-cyclometalated iridium(iii) ethylenediamine complex: synthesis and correlation between the solid state polymorphism and the photophysical properties†‡

Anna Maria Talarico,a   Iolinda Aiello,a   Anna Bellusci,a   Alessandra Crispini,*b   Mauro Ghedini,a   Nicolas Godbert,a   Teresa Pugliesea  and  Elisabeta Szerba  

* Corresponding authors

a Centro di Eccellenza CEMIF.CAL, LASCAMM CR-INSTM and Laboratorio Regionale Licryl, CNR-INFM, Dipartimento di Chimica, Università della Calabria

b Centro di Eccellenza CEMIF.CAL-LASCAMM, CR-INSTM, Dipartimento di Chimica; Dipartimento di Scienze Farmaceutiche, Università della Calabria, Italy
E-mail: a.crispini@unical.it

Abstract

The solvent induced polymorphism observed in a cyclometalated iridium(III) ethylenediamine ionic complex is a new tool to modulate and enhance emission in the solid crystalline state.

Graphical abstract: Highly luminescent bis-cyclometalated iridium(iii) ethylenediamine complex: synthesis and correlation between the solid state polymorphism and the photophysical properties

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Article information

DOI
https://doi.org/10.1039/B925471B
Article type
Communication
Submitted
05 Oct 2009
Accepted
11 Dec 2009
First published
05 Jan 2010

Dalton Trans., 2010,39, 1709-1712

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Highly luminescent bis-cyclometalated iridium(III) ethylenediamine complex: synthesis and correlation between the solid state polymorphism and the photophysical properties

A. M. Talarico, I. Aiello, A. Bellusci, A. Crispini, M. Ghedini, N. Godbert, T. Pugliese and E. Szerb, Dalton Trans., 2010, 39, 1709 DOI: 10.1039/B925471B

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