Issue 2, 2010
From the journal:

CrystEngComm

Solvothermal synthesis of two unique metal–organic frameworks: a 3-fold interpenetrating (3,4,5)-connected network and a 2-fold interpenetrating (4,5)-connected network†

Zheng-Bo Han*a  and  Guo-Xin Zhanga  

* Corresponding authors

a College of Chemistry, Liaoning University, Shenyang, P.R. China
E-mail: ceshzb@lnu.edu.cn

Abstract

A solvothermal reaction of Zn(OAc)2, 4,4′-bipyridine (bpy) and tri(2-carboxyethyl)isocyanurate (H3tci) in presence or absence of NaOH leads to the generation of two novel coordination polymers, [Zn3(tci)2(bpy)1.5(H2O)2]·6H2O (1) and [ZnNa(tci)(bpy)0.5(H2O)]·2H2O (2), which feature a three-fold interpenetrating (3,4,5)-connected 3D network and a two-fold interpenetrating (4,5)-connected (43.63)(43.66.8)-fsx network, respectively.

Graphical abstract: Solvothermal synthesis of two unique metal–organic frameworks: a 3-fold interpenetrating (3,4,5)-connected network and a 2-fold interpenetrating (4,5)-connected network

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Article information

DOI
https://doi.org/10.1039/B912158G
Article type
Communication
Submitted
22 Jun 2009
Accepted
19 Sep 2009
First published
30 Sep 2009

CrystEngComm, 2010,12, 348-351

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Solvothermal synthesis of two unique metal–organic frameworks: a 3-fold interpenetrating (3,4,5)-connected network and a 2-fold interpenetrating (4,5)-connected network

Z. Han and G. Zhang, CrystEngComm, 2010, 12, 348 DOI: 10.1039/B912158G

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