Issue 24, 2009

Undecanuclear mixed-valence 3d–4f bimetallic clusters

Abstract

Two undecanuclear 3d–4f clusters with the general formula {MnIII4MnIVLnIII6}, where Ln = Gd or Tb, were synthesized, with both showing large spin ground states, and the Tb species acting as a single molecule magnet.

Graphical abstract: Undecanuclear mixed-valence 3d–4f bimetallic clusters

Supplementary files

Article information

Article type
Communication
Submitted
18 Mar 2009
Accepted
22 Apr 2009
First published
07 May 2009

Chem. Commun., 2009, 3568-3570

Undecanuclear mixed-valence 3d–4f bimetallic clusters

T. Shiga, T. Onuki, T. Matsumoto, H. Nojiri, G. N. Newton, N. Hoshino and H. Oshio, Chem. Commun., 2009, 3568 DOI: 10.1039/B905480D

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